HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ammonia → HCID 178424370, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ammonia | HCID 222 | — |
| Reactant | Oxygen | HCID 977 | — |
| Reactant | 1,3-Bis(o-tolyl)thiourea | HCID 688028 | — |
| Catalyst | Cupric acetate | HCID 8895 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 178424370 | HCID 178424370 | 93.2% |
Reaction Steps
0.1 mol of di-o-tolylthiourea, 3 mol of ammonia, and 0.1 mmol of Cu(OAc)2 are reacted in 130 g water with oxygen. The reaction temperature is 80° C. and the oxygen pressure 3 bar. Di-o-tolylguanidine is obtained in 93.2% yield after a reaction time of 3 hours.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04898978 |
| Source dataset | uspto-grants-1990_02 |
| ORD ID | ord-948f02844cf24bc8828c5024b53132cc |
| Source note | uspto-grants-1990_02 |