Isopropanol → HCID 14232115, compound

HRID 1199398Notes

Reaction equation

HRID 1199398 reaction equation
[CH3:1][N:2]([N:12]1[CH:16]=[CH:15][CH:14]=[CH:13]1)[C:3]1[CH:8]=[CH:7][N:6]=[CH:5][C:4]=1[N+:9]([O-])=O.C(O)(C)C>[Pd].CO>[CH3:1][N:2]([C:3]1[CH:8]=[CH:7][N:6]=[CH:5][C:4]=1[NH2:9])[N:12]1[CH:13]=[CH:14][CH:15]=[CH:16]1

Participants

5

Reactant 2

HCID 3776IsopropanolHCID 14232104HCID 14232104, compound

Product 1

HCID 14232115HCID 14232115, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 887MethanolSolvent

Procedure

In a Parr shaker apparatus was placed a mixture prepared from 5.0 g of N-methyl-N-(1H-pyrrol-1-yl)-3-nitro-4-pyridinamine, 310 mg of 10% palladium on carbon, 175 ml of isopropanol and 30 ml of methanol. This was shaken for 18 hours at ambient temperature.

Sources & evidence

ORD record
ord-af21c7df05784bca8f3ab8d7fff6a202
Source dataset
uspto-grants-1990_02
Patent number
US04900742

Reaction notes

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