HCID 86742788, compound → Propylene Oxide

HRID 1199510Notes

Reaction equation

HRID 1199510 reaction equation
[C:1]([OH:5])(C)([CH3:3])[CH3:2].[C:6]([O:10][O:11]C(C)(C)C)([CH3:9])([CH3:8])[CH3:7]>C(O)(C)(C)C>[CH2:2]1[O:5][CH:1]1[CH3:3].[C:6]([O:10][OH:11])([CH3:9])([CH3:8])[CH3:7]

Participants

4

Reactant 1

HCID 86742788HCID 86742788, compound

Product 2

HCID 6378Propylene OxideHCID 6410tert-Butyl hydroperoxide

Reagents, catalysts & solvents 1

HCID 6386tert-ButanolSolvent

Procedure

In order to demonstrate the need for obtaining the tertiary butyl alcohol/ditertiary butyl peroxide azeotrope fraction described above, the tertiary butyl alcohol starting material obtained from the reaction of propylene oxide with tertiary butyl hydroperoxide, as described above, was sequentially extracted in a batch water extractor. In each extraction, 15 grams of raffinate or upper layer was extracted with the amount of water as indicated in Table I.

Sources & evidence

ORD record
ord-fc6f67b7c84e4ccdac3732f2d8fec198
Source dataset
uspto-grants-1990_02
Patent number
US04900850

Reaction notes

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