Sulfuryl chloride → HCID 19864302, compound

Participants

Reaction Steps

Sulphuryl chloride (0.16 ml) was added to a stirred solution of 6-methyl-8-phenyl-5,6,7,8-tetrahydro-4H-thieno[2,3-d]azepine hydrochloride (0.49 g free base converted to hydrochloride salt with ethanolic hydrogen chloride) at room temperature. After 2 hours the mixture was evaporated and the solid residue recrystallised twice from ethanol (5 ml) to give the title product as white crystals (m.p. 198°).

Provenance & Evidence