Dichloromethane → HCID 19864969, compound

HRID 1200285Notes

Reaction equation

HRID 1200285 reaction equation
[CH3:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([CH3:8])[C:3]=1[OH:9].[CH2:10]([O:14][CH2:15][CH2:16][CH:17]([CH2:19][CH2:20][CH:21]=[C:22]([CH3:24])[CH3:23])[CH3:18])[CH2:11][CH2:12][CH3:13].Cl(O)(=O)(=O)=O.C(Cl)Cl>O>[CH2:10]([O:14][CH2:15][CH2:16][CH:17]([CH3:18])[CH2:19][CH2:20][CH2:21][C:22]([C:6]1[CH:5]=[C:4]([CH3:8])[C:3]([OH:9])=[C:2]([CH3:1])[CH:7]=1)([CH3:24])[CH3:23])[CH2:11][CH2:12][CH3:13]

Participants

6

Reactant 4

HCID 6344DichloromethaneHCID 113352,6-DimethylphenolHCID 24247Perchloric AcidHCID 1167352-Octene, 8-butoxy-2,6-dimethyl-

Product 1

HCID 19864969HCID 19864969, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

12.2 Parts of 2,6-dimethylphenol, 5.3 parts of citronellyl n-butyl ether, and 1.0 parts of 70% perchloric acid in 30 parts of methylene chloride were stored at room temperature for 3 days. The reaction mixture after pouring into water was extracted with ether, and the ether solution washed with sodium bicarbonate solution, then water and evaporated. Distillation of the residual oil gave 1-n-butyloxy-7-(4-hydroxy-3,5-dimethyl-phenyl)-3,7-dimethyl-octane as a fraction with b0.8, 168°-76° C.

Workup

  1. extractionwas extracted with ether
  2. washthe ether solution washed with sodium bicarbonate solution
  3. customwater and evaporated
  4. distillationDistillation of the residual oil

Sources & evidence

ORD record
ord-2b041c825c2d4c9cb001e83851e27913
Source dataset
uspto-grants-1990_02
Patent number
US04904815

Reaction notes

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