Acetate → Methyl 3-(2-(methoxycarbonyl)vinyl)-4,7-dimethylindole-2-carboxylate

HRID 1201593Notes

Reaction equation

HRID 1201593 reaction equation
[C:16]([CH:17]=[CH2:18])(=[O:19])[O:20][CH3:21].[C:25]([O-:26])(=[O:27])[CH3:28].[C:30]([O-:31])(=[O:32])[CH3:33].[CH3:1][c:2]1[c:3]2[cH:4][c:5]([C:12](=[O:13])[O:14][CH3:15])[nH:6][c:7]2[c:8]([CH3:11])[cH:9][cH:10]1.[CH3:22][C:23]#[N:24].[Pd+2:29]>>[CH3:1][c:2]1[c:3]2[c:4]([CH:18]=[CH:17][C:16](=[O:19])[O:20][CH3:21])[c:5]([C:12](=[O:13])[O:14][CH3:15])[nH:6][c:7]2[c:8]([CH3:11])[cH:9][cH:10]1

Participants

6

Reactant 5

HCID 175Acetate2×HCID 6342AcetonitrileHCID 7294Methyl AcrylateHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 4714976methyl 4,7-dimethyl-1H-indole-2-carboxylate

Product 1

HCID 54299854Methyl 3-(2-(methoxycarbonyl)vinyl)-4,7-dimethylindole-2-carboxylate

Sources & evidence

ORD record
ord-6890803b5ce345908ea7ec47b7e25c88
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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