Ethanol → 4-Bromo-3',5'-dimethoxy-biphenyl-2,3-diamine

HRID 1215257Notes

Reaction equation

HRID 1215257 reaction equation
[Br:14][c:15]1[c:16]([NH2:23])[c:17]([NH2:22])[c:18]([Br:21])[cH:19][cH:20]1.[C:24](=[O:25])([O-:26])[O-:27].[CH3:1][O:2][c:3]1[cH:4][c:5]([B:11]([OH:12])[OH:13])[cH:6][c:7]([O:9][CH3:10])[cH:8]1.[CH3:30][CH2:31][OH:32].[CH3:33][c:34]1[cH:35][cH:36][cH:37][cH:38][cH:39]1.[CH3:40][CH2:41][O:42][C:43]([CH3:44])=[O:45].[Na+:28].[Na+:29].[OH2:46]>>[CH3:1][O:2][c:3]1[cH:4][c:5](-[c:18]2[c:17]([NH2:22])[c:16]([NH2:23])[c:15]([Br:14])[cH:20][cH:19]2)[cH:6][c:7]([O:9][CH3:10])[cH:8]1

Participants

9

Reactant 8

HCID 702EthanolHCID 923Sodium ion2×HCID 962WaterHCID 1140TolueneHCID 8857Ethyl AcetateHCID 19660Carbonate IonHCID 4374257(3,5-Dimethoxyphenyl)boronic acidHCID 118215323,6-Dibromobenzene-1,2-diamine

Product 1

HCID 592928784-Bromo-3',5'-dimethoxy-biphenyl-2,3-diamine

Sources & evidence

ORD record
ord-b263e6928bfb45128ee23e124892d629
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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