Dichloromethane → 2-(1-Adamantyl)-5-bromo-1-(2-tetrahydropyranoxy)benzene

HRID 1220151Notes

Reaction equation

HRID 1220151 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]([O:6][CH:9]2[O:10][CH2:11][CH2:12][CH2:13][CH2:14]2)[c:7]([C:8]([CH3:15])([CH3:16])[CH3:17])[cH:18]1.[C:19]12([c:29]3[c:30]([OH:36])[cH:31][c:32]([Br:35])[cH:33][cH:34]3)[CH2:20][CH:21]3[CH2:22][CH:23]([CH2:24][CH:25]([CH2:26]1)[CH2:27]3)[CH2:28]2.[CH2:54]1[CH2:55][CH:56]=[CH:57][O:58][CH2:59]1.[Cl:60][CH2:61][Cl:62].[c:37]1([CH3:38])[cH:39][cH:40][c:41]([S:42]([O-:43])(=[O:44])=[O:45])[cH:46][cH:47]1.[nH+:48]1[cH:49][cH:50][cH:51][cH:52][cH:53]1>>[CH:9]1([O:36][c:30]2[c:29]([C:19]34[CH2:20][CH:21]5[CH2:22][CH:23]([CH2:24][CH:25]([CH2:26]3)[CH2:27]5)[CH2:28]4)[cH:34][cH:33][c:32]([Br:35])[cH:31]2)[O:10][CH2:11][CH2:12][CH2:13][CH2:14]1

Participants

7

Reactant 6

HCID 6344DichloromethaneHCID 80803,4-dihydro-2H-pyranHCID 85570p-ToluenesulfonateHCID 4989215PyridiniumHCID 158188564-Bromo-2-t-butyl-1-(2-tetrahydropyranoxy)benzeneHCID 223478532-(1-Adamantyl)-5-bromophenol

Product 1

HCID 221045742-(1-Adamantyl)-5-bromo-1-(2-tetrahydropyranoxy)benzene

Sources & evidence

ORD record
ord-1fb853740ee5488bb65e36915b626178
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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