Acetate → 9-Phenyl-9H,9'H-[3,3']bicarbazolyl

HRID 1223016Notes

Reaction equation

HRID 1223016 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]2[nH:6][c:7]3[cH:8][cH:9][cH:10][cH:11][c:12]3[c:13]2[cH:14]1.[C:59](=[O:60])([O-:61])[O-:62].[CH3:65][c:66]1[cH:67][cH:68][cH:69][cH:70][cH:71]1.[CH3:81][O:82][CH2:83][CH2:84][O:85][CH3:86].[K+:63].[K+:64].[O-:73][C:74]([CH3:75])=[O:76].[O-:77][C:78]([CH3:79])=[O:80].[Pd+2:72].[c:15]1(-[n:21]2[c:22]3[cH:23][cH:24][cH:25][cH:26][c:27]3[c:28]3[cH:29][c:30]([B:34]([OH:35])[OH:36])[cH:31][cH:32][c:33]23)[cH:16][cH:17][cH:18][cH:19][cH:20]1.[c:37]1([CH3:38])[cH:39][cH:40][cH:41][cH:42][c:43]1[P:44]([c:45]1[cH:46][cH:47][cH:48][cH:49][c:50]1[CH3:51])[c:52]1[cH:53][cH:54][cH:55][cH:56][c:57]1[CH3:58]>>[c:2]1(-[c:30]2[cH:29][c:28]3[c:27]4[c:22]([n:21](-[c:15]5[cH:16][cH:17][cH:18][cH:19][cH:20]5)[c:33]3[cH:32][cH:31]2)[cH:23][cH:24][cH:25][cH:26]4)[cH:3][cH:4][c:5]2[nH:6][c:7]3[cH:8][cH:9][cH:10][cH:11][c:12]3[c:13]2[cH:14]1

Participants

10

Reactant 9

HCID 175Acetate2×HCID 813Potassium Cation2×HCID 1140TolueneHCID 80711,2-DimethoxyethaneHCID 19660Carbonate IonHCID 80271Tri-o-tolylphosphineHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 2524463-BromocarbazoleHCID 513584509-Phenyl-9H-carbazole-3-boronic acid

Product 1

HCID 593066299-Phenyl-9H,9'H-[3,3']bicarbazolyl

Sources & evidence

ORD record
ord-cb73e8e34671445e88539fa949450cae
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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