Potassium Cation → 2-[4-(1-Tritylpyrazolo[5,4-b]pyridin-4-yl)pyrazol-1-yl]acetonitrile

HRID 1225008Notes

Reaction equation

HRID 1225008 reaction equation
[Br:40][CH2:41][C:42]#[N:43].[C:34](=[O:35])([O-:36])[O-:37].[CH2:44]1[O:45][CH2:46][CH2:47][CH2:48]1.[K+:38].[K+:39].[nH:1]1[n:2][cH:3][c:4](-[c:6]2[c:7]3[c:8]([n:9][cH:10][cH:11]2)[n:12]([C:15]([c:16]2[cH:17][cH:18][cH:19][cH:20][cH:21]2)([c:22]2[cH:23][cH:24][cH:25][cH:26][cH:27]2)[c:28]2[cH:29][cH:30][cH:31][cH:32][cH:33]2)[n:13][cH:14]3)[cH:5]1>>[n:1]1[n:2]([CH2:41][C:42]#[N:43])[cH:3][c:4](-[c:6]2[c:7]3[c:8]([n:9][cH:10][cH:11]2)[n:12]([C:15]([c:16]2[cH:17][cH:18][cH:19][cH:20][cH:21]2)([c:22]2[cH:23][cH:24][cH:25][cH:26][cH:27]2)[c:28]2[cH:29][cH:30][cH:31][cH:32][cH:33]2)[n:13][cH:14]3)[cH:5]1

Participants

6

Reactant 5

HCID 813Potassium Cation2×HCID 8028TetrahydrofuranHCID 11534BromoacetonitrileHCID 19660Carbonate IonHCID 666458864-(1H-pyrazol-4-yl)-1-trityl-1H-pyrazolo[3,4-b]pyridine

Product 1

HCID 666456212-[4-(1-Tritylpyrazolo[5,4-b]pyridin-4-yl)pyrazol-1-yl]acetonitrile

Sources & evidence

ORD record
ord-bb23e2dee8ac44a6b32d86709b0711dd
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

Loading…