HRID1225071

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID962

Water

H2O

HCID1140

Toluene

C7H8

HCID8028

Tetrahydrofuran

C4H8O

HCID74506

Triphenylmethylphosphonium

C19H18P+

HCID249273

(2-Methoxy-5-methylphenyl)(phenyl)methanone

C15H14O2

HCID178418339

Butyllithium

C4H9Li

PRODUCTS

产物

HCID11356533

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD记录: ord-1af8bfa0d44d4c249d34093411c18991
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (5/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (5/10)

反应SMILES

[Br-:29].[CH2:1]1[O:2][CH2:3][CH2:4][CH2:5]1.[CH2:6]([Li:7])[CH2:8][CH2:9][CH3:10].[CH3:11][O:12][c:13]1[c:14]([C:15](=[O:16])[c:17]2[cH:18][cH:19][cH:20][cH:21][cH:22]2)[cH:23][c:24]([CH3:27])[cH:25][cH:26]1.[CH3:30][P+:31]([c:32]1[cH:33][cH:34][cH:35][cH:36][cH:37]1)([c:38]1[cH:39][cH:40][cH:41][cH:42][cH:43]1)[c:44]1[cH:45][cH:46][cH:47][cH:48][cH:49]1.[CH3:50][c:51]1[cH:52][cH:53][cH:54][cH:55][cH:56]1.[OH2:28]>>[CH2:1]=[C:15]([c:14]1[c:13]([O:12][CH3:11])[cH:26][cH:25][c:24]([CH3:27])[cH:23]1)[c:17]1[cH:18][cH:19][cH:20][cH:21][cH:22]1