HRID1234603

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6344

Dichloromethane

CH2Cl2

HCID11205

Carbon tetrabromide

CBr4

HCID11776

Triphenylphosphine

C18H15P

反应SMILES：CCc1c(C)c2c(c(OCC[Si](C)(C)C)c1CC=C(C)CO)C(=O)OC2

HCID67009880

未命名化合物

PRODUCTS

产物

反应SMILES：CCc1c(C)c2c(c(OCC[Si](C)(C)C)c1CC=C(C)CBr)C(=O)OC2

HCID67011311

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD记录: ord-352ac7d4e88142389a1e3621402f9d7b
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (5/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (5/10)

反应SMILES

[C:46]([Br:47])([Br:48])([Br:49])[Br:50].[CH2:1]([CH3:2])[c:3]1[c:4]([CH3:26])[c:5]2[c:9]([c:10]([O:18][CH2:19][CH2:20][Si:21]([CH3:22])([CH3:23])[CH3:24])[c:11]1[CH2:12][CH:13]=[C:14]([CH2:15][OH:16])[CH3:17])[C:8](=[O:25])[O:7][CH2:6]2.[Cl:51][CH2:52][Cl:53].[c:27]1([P:28]([c:29]2[cH:30][cH:31][cH:32][cH:33][cH:34]2)[c:35]2[cH:36][cH:37][cH:38][cH:39][cH:40]2)[cH:41][cH:42][cH:43][cH:44][cH:45]1>>[CH2:1]([CH3:2])[c:3]1[c:4]([CH3:26])[c:5]2[c:9]([c:10]([O:18][CH2:19][CH2:20][Si:21]([CH3:22])([CH3:23])[CH3:24])[c:11]1[CH2:12][CH:13]=[C:14]([CH2:15][Br:47])[CH3:17])[C:8](=[O:25])[O:7][CH2:6]2