Bromide ion → 13-allyl-8-isopropenyl-9,10-dimethoxy-5,8-dihydro-6H-[1,3]dioxolo[4,5-g]isoquino[3,2-a]isoquinoline
Reaction equation
[Br-:29].[Br-:30].[C:31](=[CH2:32])([CH3:33])[Mg+:34].[CH2:1]([CH:2]=[CH2:3])[C:4]1=[C:13]2[NH+:12]([CH2:11][c:10]3[c:5]1[cH:6][cH:7][c:8]([O:27][CH3:28])[c:9]3[O:25][CH3:26])[CH2:21][CH2:20][c:19]1[c:14]2[cH:15][c:16]2[c:17]([cH:18]1)[O:22][CH2:23][O:24]2.[CH3:40][CH2:41][O:42][CH2:43][CH3:44].[O:35]1[CH2:36][CH2:37][CH2:38][CH2:39]1>>[CH2:1]([CH:2]=[CH2:3])[C:4]1=[C:13]2[N:12]([CH:11]([C:31](=[CH2:32])[CH3:33])[c:10]3[c:5]1[cH:6][cH:7][c:8]([O:27][CH3:28])[c:9]3[O:25][CH3:26])[CH2:21][CH2:20][c:19]1[c:14]2[cH:15][c:16]2[c:17]([cH:18]1)[O:22][CH2:23][O:24]2Participants
6
Reactant 5
Product 1
Sources & evidence
- ORD record
- ord-6fb61a34dd2e402a9b469c2bb34a9812
- Source dataset
- Training data from https://doi.org/10.1039/C8SC04228D (5/10)
Reaction notes
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