Ammonia → 4-Bromo-5-aminophthalide

HRID 1240153Notes

Reaction equation

HRID 1240153 reaction equation
[Br:1][c:2]1[c:3]2[c:8]([cH:9][cH:10][c:11]1[N+:12]([O-:13])=[O:14])[C:6](=[O:7])[O:5][CH2:4]2.[CH3:17][CH2:18][OH:19].[Fe+2:25].[NH3:16].[OH2:15].[S:20]([O-:21])([O-:22])(=[O:23])=[O:24]>>[Br:1][c:2]1[c:3]2[c:8]([cH:9][cH:10][c:11]1[NH2:12])[C:6](=[O:7])[O:5][CH2:4]2

Participants

7

Reactant 6

HCID 222AmmoniaHCID 702EthanolHCID 962WaterHCID 1117Sulfate IonHCID 27284Ferrous cationHCID 185511854-Bromo-5-nitrophthalide

Product 1

HCID 185511684-Bromo-5-aminophthalide

Sources & evidence

ORD record
ord-d374cf4bd7644f3badf69d19809c8e21
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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