Acetate → [3-(N'-benzhydrylidene-hydrazino)-thiophen-2-yl]-(1-benzyloxymethyl-1H-benzoimidazol-2-yl)-methanone

HRID 1240890Notes

Reaction equation

HRID 1240890 reaction equation
[C:27]([c:28]1[cH:29][cH:30][cH:31][cH:32][cH:33]1)([c:34]1[cH:35][cH:36][cH:37][cH:38][cH:39]1)=[N:40][NH2:41].[C:42](=[O:43])([O-:44])[O-:45].[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][CH2:9][n:10]1[c:11]([C:19](=[O:20])[c:21]2[s:22][cH:23][cH:24][c:25]2[Br:26])[n:12][c:13]2[c:14]1[cH:15][cH:16][cH:17][cH:18]2.[CH3:48][c:49]1[cH:50][cH:51][cH:52][cH:53][cH:54]1.[CH3:55][CH2:56][O:57][C:58](=[O:59])[CH3:60].[Cs+:46].[Cs+:47].[O-:62][C:63]([CH3:64])=[O:65].[O-:66][C:67]([CH3:68])=[O:69].[Pd+2:61]>>[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][CH2:9][n:10]1[c:11]([C:19](=[O:20])[c:21]2[s:22][cH:23][cH:24][c:25]2[NH:41][N:40]=[C:27]([c:28]2[cH:29][cH:30][cH:31][cH:32][cH:33]2)[c:34]2[cH:35][cH:36][cH:37][cH:38][cH:39]2)[n:12][c:13]2[c:14]1[cH:15][cH:16][cH:17][cH:18]2

Participants

9

Reactant 8

HCID 175Acetate2×HCID 1140TolueneHCID 8857Ethyl AcetateHCID 19660Carbonate IonHCID 79304DiphenylmethylidenehydrazineHCID 104967Cesium cation2×HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 57637380(1-benzyloxymethyl-1H-benzimidazol-2-yl)-(3-bromothiophen-2-yl)methanone

Product 1

HCID 57637293[3-(N'-benzhydrylidene-hydrazino)-thiophen-2-yl]-(1-benzyloxymethyl-1H-benzoimidazol-2-yl)-methanone

Sources & evidence

ORD record
ord-026137dcefbf4fde975057ac70d3dccf
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (5/10)

Reaction notes

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