Methanol → HCID 21938005, compound

HRID 1242176Notes

Reaction equation

HRID 1242176 reaction equation
[CH3:1][N:2]([CH3:20])[C:3]1[CH:8]=[CH:7][C:6]([NH:9][C:10]2[CH:15]=[C:14](Cl)[CH:13]=[CH:12][C:11]=2[N+:17]([O-:19])=[O:18])=[CH:5][CH:4]=1.[Na].[CH3:22][OH:23]>>[CH3:1][N:2]([CH3:20])[C:3]1[CH:8]=[CH:7][C:6]([NH:9][C:10]2[CH:15]=[C:14]([O:23][CH3:22])[CH:13]=[CH:12][C:11]=2[N+:17]([O-:19])=[O:18])=[CH:5][CH:4]=1

Participants

4

Reactant 3

HCID 887MethanolHCID 5360545SodiumHCID 21938066HCID 21938066, compound

Product 1

HCID 21938005HCID 21938005, compound

Procedure

24.9 g of N,N-dimethyl-N′-(5-chloro-2-nitrophenyl)benzene-1,4-diamine was added to a solution that consists of 8 g of sodium in 200 ml of methanol, and the mixture was heated in an autoclave for 9 hours to 120° C. After cooling, crystalline product was suctioned out.

Workup

  1. temperaturethe mixture was heated in an autoclave for 9 hours to 120° C
  2. temperatureAfter cooling

Sources & evidence

ORD record
ord-20fcda91c3c645608be4dc9afb7af322
Source dataset
uspto-grants-2006_10
Patent number
US07115645B2

Reaction notes

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