Chloroform → HCID 58709433, compound

HRID 1243807Notes

Reaction equation

HRID 1243807 reaction equation
[N:1]([C:4]1[N:9]=[C:8]([N:10]=[N+:11]=[N-:12])[N:7]=[C:6]([NH:13][NH:14][C:15]2[N:20]=[C:19]([N:21]=[N+:22]=[N-:23])[N:18]=[C:17]([N:24]=[N+:25]=[N-:26])[N:16]=2)[N:5]=1)=[N+:2]=[N-:3].C(Cl)(Cl)Cl.ClCl>O>[N:1]([C:4]1[N:9]=[C:8]([N:10]=[N+:11]=[N-:12])[N:7]=[C:6]([N:13]=[N:14][C:15]2[N:20]=[C:19]([N:21]=[N+:22]=[N-:23])[N:18]=[C:17]([N:24]=[N+:25]=[N-:26])[N:16]=2)[N:5]=1)=[N+:2]=[N-:3]

Participants

5

Reactant 3

HCID 6212ChloroformHCID 24526ChlorineHCID 21065198HCID 21065198, compound

Product 1

HCID 58709433HCID 58709433, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Briefly, 4,4′,6,6′-tetra(chloro)hydrazo-1,3,5-triazine (1) [9] reacts rapidly with an excess of hydrazine monohydrate in acetonitrile to give 4,4′,6,6′-tetra(hydrazino)-hydrazo-1,3,5-triazine (2). Compound (2) undergoes diazotization to yield 4,4′,6,6′-tetra(azido)hydrazo-1,3,5-triazine (3). A suspension of (3) in 1:2 (v/v) H2O:CHCl3 solution reacts with chlorine gas at room temperature to provide 4,4′,6,6′-tetra(azido)azo-1,3,5-triazine (4, TAAT).

Sources & evidence

ORD record
ord-6bf2f8a48ca54a5a853665458d45cf45
Source dataset
uspto-grants-2006_10
Patent number
US07119179B1

Reaction notes

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