(E)-1-Chloro-3-(2-(4-nitrophenyl)ethenyl)benzene → HCID 21920052, compound

HRID 1244616Notes

Reaction equation

HRID 1244616 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4](/[CH:8]=[CH:9]/[C:10]2[CH:15]=[CH:14][C:13]([N+:16]([O-])=O)=[CH:12][CH:11]=2)[CH:3]=1>[Pt]>[Cl:1][C:2]1[CH:3]=[C:4]([CH2:8][CH2:9][C:10]2[CH:11]=[CH:12][C:13]([NH2:16])=[CH:14][CH:15]=2)[CH:5]=[CH:6][CH:7]=1

Participants

3

Reactant 1

HCID 6440392(E)-1-Chloro-3-(2-(4-nitrophenyl)ethenyl)benzene

Product 1

HCID 21920052HCID 21920052, compound

Reagents, catalysts & solvents 1

HCID 23939PlatinumCatalyst

Procedure

In an analogous manner to that described in Example 36 b), the hydrogenation of (E)-1-chloro-3-[2-(4-nitrophenyl)ethenyl]-benzene using platinum on carbon (5%) as the catalyst but with a reaction time of 18 hours and simultaneous reduction of the double bond yields the 4-[2-(3-chloro-phenyl)-ethyl]-phenylamine as a dark brown oil; MS: m/e=232 (M+H)+.

Sources & evidence

ORD record
ord-caaf9169df2c412b9e2b4c923a7fef89
Source dataset
uspto-grants-2006_10
Patent number
US07122562B2

Reaction notes

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