Potassium Carbonate → HCID 21910016, compound

HRID 1245251Notes

Reaction equation

HRID 1245251 reaction equation
[C:1]1([CH3:15])[CH:6]=[CH:5][C:4]([NH:7][C:8]2[CH:13]=[CH:12][C:11]([CH3:14])=[CH:10][CH:9]=2)=[CH:3][CH:2]=1.C(=O)([O-])[O-].[K+].[K+].Br[C:23]1[C:40]2[C:41]3[C:26]([C:27]4[CH:28]=[CH:29][CH:30]=[C:31]5[C:42]=4[C:35]([C:36]=3[CH:37]=[CH:38][CH:39]=2)=[C:34]2[CH:43]=[CH:44][CH:45]=[CH:46][C:33]2=[CH:32]5)=[CH:25][CH:24]=1>O.[Cu]>[C:11]1([CH3:14])[CH:12]=[CH:13][C:8]([N:7]([C:23]2[C:40]3[C:41]4[C:26]([C:27]5[CH:28]=[CH:29][CH:30]=[C:31]6[C:42]=5[C:35]([C:36]=4[CH:37]=[CH:38][CH:39]=3)=[C:34]3[CH:43]=[CH:44][CH:45]=[CH:46][C:33]3=[CH:32]6)=[CH:25][CH:24]=2)[C:4]2[CH:3]=[CH:2][C:1]([CH3:15])=[CH:6][CH:5]=2)=[CH:9][CH:10]=1

Participants

6

Reactant 3

HCID 11430Potassium CarbonateHCID 69293Benzenamine, 4-methyl-N-(4-methylphenyl)-HCID 21910017HCID 21910017, compound

Product 1

HCID 21910016HCID 21910016, compound

Reagents, catalysts & solvents 2

HCID 23978CopperCatalystHCID 962WaterSolvent

Procedure

Then, di-p-tolylamine, potassium carbonate, and copper power were added to the thus obtained bromobenzo[a]perylene. This mixture stood still for reaction at 200 degrees centigrade for thirty hours. After reactant solution was diluted with water, reactant was extracted by chloroform. Thereafter, the reactant was refined in a conventional manner to thereby obtain di-p-tolylaminobenzo [a] perylene.

Workup

  1. customThis mixture stood still for reaction at 200 degrees centigrade for thirty hours
  2. extractionwas extracted by chloroform

Sources & evidence

ORD record
ord-64470d0753df4d328866012508a97d55
Source dataset
uspto-grants-2006_10
Patent number
US07125614B2

Reaction notes

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