Phosgene → HCID 21288567, compound

HRID 1248076Notes

Reaction equation

HRID 1248076 reaction equation
C(N[C:6]([NH:8][S:9]([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][N:13]=1)(=[O:11])=[O:10])=[O:7])CCC.C(Cl)(Cl)=O>C1(C)C(C)=CC=CC=1>[N:13]1[CH:14]=[CH:15][CH:16]=[CH:17][C:12]=1[S:9]([N:8]=[C:6]=[O:7])(=[O:10])=[O:11]

Participants

4

Reactant 2

HCID 6371PhosgeneHCID 20278365N-(Butylcarbamoyl)pyridine-2-sulfonamide

Product 1

HCID 21288567HCID 21288567, compound

Reagents, catalysts & solvents 1

HCID 7237O-XyleneSolvent

Procedure

To 125 ml of dry xylene is added with stirring 20.7 g of N-(butylcarbamoyl)-2-pyridinesulfonamide. This solution is heated to reflux, and phosgene is added until no further uptake of this gas is observed. It is then cooled, filtered and the solvent is removed in vacuo to yield 2-pyridinesulfonylisocyanate.

Workup

  1. temperatureThis solution is heated
  2. temperatureto reflux
  3. temperatureIt is then cooled
  4. filtrationfiltered
  5. customthe solvent is removed in vacuo

Sources & evidence

ORD record
ord-904aa3ec8cf14ef79c21f3913ca77421
Source dataset
uspto-grants-1985_06
Patent number
US04522645

Reaction notes

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