HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Chloride → HCID 20278419, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Chloride | HCID 5234 | — |
| Reactant | Methyl acetoacetate | HCID 7757 | — |
| Reactant | Sodium | HCID 5360545 | — |
| Reactant | HCID 20278420 | HCID 20278420 | — |
| Reactant | 2-[4-(6,7-Dichloro-2-quinoxalinyloxy)phenoxy]propionic acid chloride | HCID 54101154 | — |
| Solvent | Dimethyl Sulfoxide | HCID 679 | — |
| Product | HCID 20278419 | HCID 20278419 | — |
Reaction Steps
Again, following the same procedures, methyl 2-acetyl-4-[4-(6,7-dichloro-2-quinoxalinyloxy)phenoxy]-3-oxopentanoate (XIV; X' is chloro and X" is chloro) is prepared from 2-[4-(6,7-dichloro-2-quinoxalinyloxy)phenoxy]propionic acid chloride and the sodium salt of methylacetoacetate, and is then heated with sodium chloride and DMSO to yield 5-[4-(6,7-dichloro-2-quinoxalinyloxy)phenoxy]-2,4-hexanedione (XV; X' is chloro and X" is chloro).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04522647 |
| Source dataset | uspto-grants-1985_06 |
| ORD ID | ord-71a1b6197d1e4dcbad5f2fdbfe2f6879 |
| Source note | uspto-grants-1985_06 |