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HRID1248085

反应详情

EQUATION

反应方程式

HRID 1248085 的结构方程式

REACTANTS

反应物

5
结构：[Cl-].[Na+]
HCID5234

Sodium chloride

ClNa

结构：COC(=O)CC(C)=O
HCID7757

Methyl acetoacetate

C5H8O3

结构：[Na]
HCID5360545

Sodium

Na

结构：COC(=O)C(C(C)=O)C(=O)C(C)Oc1ccc(Oc2cnc3cc(Cl)c(Cl)cc3n2)cc1
HCID20278420

未命名化合物

结构：CC(Oc1ccc(Oc2cnc3cc(Cl)c(Cl)cc3n2)cc1)C(=O)Cl
HCID54101154

未命名化合物

PRODUCTS

生成物

1
结构：CC(=O)CC(=O)C(C)Oc1ccc(Oc2cnc3cc(Cl)c(Cl)cc3n2)cc1
HCID20278419

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CS(C)=O
溶剂HCID679

Dimethyl sulfoxide

C2H6OS

PROCEDURE

实验过程

Again, following the same procedures, methyl 2-acetyl-4-[4-(6,7-dichloro-2-quinoxalinyloxy)phenoxy]-3-oxopentanoate (XIV; X' is chloro and X" is chloro) is prepared from 2-[4-(6,7-dichloro-2-quinoxalinyloxy)phenoxy]propionic acid chloride and the sodium salt of methylacetoacetate, and is then heated with sodium chloride and DMSO to yield 5-[4-(6,7-dichloro-2-quinoxalinyloxy)phenoxy]-2,4-hexanedione (XV; X' is chloro and X" is chloro).