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HRID1249315

反应详情

EQUATION

反应方程式

HRID 1249315 的结构方程式

REACTANTS

反应物

6
反应SMILES：N#CCC(N)=O
HCID7898

2-Cyanoacetamide

C3H4N2O

3 次

反应SMILES：CC(=O)CC(C)=O
HCID31261

2,4-Pentanedione

C5H8O2

反应SMILES：Cc1cc(C)c(C#N)c(=O)[nH]1
HCID69856

3-Cyano-4,6-dimethyl-2-hydroxypyridine

C8H8N2O

反应SMILES：CC(=O)C(C)C(C)=O
HCID69949

3-Methyl-2,4-pentanedione

C6H10O2

反应SMILES：CC(=O)CC(=O)C(F)(F)F
HCID73943

1,1,1-Trifluoroacetylacetone

C5H5F3O2

反应SMILES：Cc1[nH]c(=O)c(C#N)c(C)c1C
HCID642508

2-hydroxy-4,5,6-trimethylnicotinonitrile

C9H10N2O

PRODUCTS

产物

1
反应SMILES：Cc1cc(C(F)(F)F)c(C#N)c(=O)[nH]1
HCID247440

6-Methyl-2-oxo-4-(trifluoromethyl)-1,2-dihydropyridine-3-carbonitrile

C8H5F3N2O

PROCEDURE

实验过程

3-Cyano-6-methyl-4-trifluoromethylpyrid-2-one was prepared from 1,1,1-trifluoroacetylacetone and cyanoacetamide following the procedure of Kametani and Sato (Yakugaku Kenkyu 34, 117, 1962). 3-Cyano-4,6-dimethylpyrid-2-one and 3-cyano-4,5,6-trimethylpyrid-2-one were similarly prepared from acetylacetone and cyanoacetamide, and 3-methylpentan-2,4-dione and cyanoacetamide respectively.