HRID1249339

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID33865

11-Methyldodecanol

C13H28O

结构：COC(=O)C1=C(C(=O)OC)C(C(=O)OC)C(C(=O)OC)=C1C(=O)OC

HCID494485

Pentamethyl cyclopentadiene-1,2,3,4,5-pentacarboxylate

C15H16O10

PRODUCTS

生成物

结构：CC(C)CCCCCCCCCCOC(=O)C1=C(C(=O)OCCCCCCCCCCC(C)C)C(C(=O)OCCCCCCCCCCC(C)C)C(C(=O)OCCCCCCCCCCC(C)C)=C1C(=O)OCCCCCCCCCCC(C)C

HCID20155084

未命名化合物

收率 100.2%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID887

Methanol

CH4O

PROCEDURE

实验过程

7.13 g (20 mmol) of 1,2,3,4,5-pentamethoxycarbonylcyclopentadiene are treated with 20.0 g (100 mmol) of isotridecyl alcohol. 3.12 g (97.5% of the theoretical yield) of methanol are distilled off at 100° C. within 8 h, firstly at 1013 mbar, then at from 363 to 18 mbar. 24 g of 1,2,3,4,5-pentaisotridecyloxycarbonylcyclopentadiene are obtained.

WORKUP

后处理

distillationare distilled off at 100° C. within 8 h, firstly at 1013 mbar

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-06999c9c110c4195ad4f0e20ffd54137
来源数据集: uspto-grants-1986_12
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04631243
来源说明: uspto-grants-1986_12

反应 SMILES

[CH3:1][O:2][C:3]([C:5]1[CH:9]([C:10]([O:12][CH3:13])=[O:11])[C:8]([C:14]([O:16][CH3:17])=[O:15])=[C:7]([C:18]([O:20][CH3:21])=[O:19])[C:6]=1[C:22]([O:24][CH3:25])=[O:23])=[O:4].C(O)[CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH:36]([CH3:38])[CH3:37]>CO>[CH2:25]([O:24][C:22]([C:6]1[CH:5]([C:3]([O:2][CH2:1][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH:36]([CH3:37])[CH3:38])=[O:4])[C:9]([C:10]([O:12][CH2:13][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH:36]([CH3:37])[CH3:38])=[O:11])=[C:8]([C:14]([O:16][CH2:17][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH:36]([CH3:37])[CH3:38])=[O:15])[C:7]=1[C:18]([O:20][CH2:21][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH:36]([CH3:37])[CH3:38])=[O:19])=[O:23])[CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH:36]([CH3:37])[CH3:38]