1,2-Epoxycyclododeca-5,9-diene → Cyclododecanol

HRID 1250040Notes

Reaction equation

HRID 1250040 reaction equation
[O:1]1[CH:3]2[CH2:4][CH2:5][CH:6]=[CH:7][CH2:8][CH2:9][CH:10]=[CH:11][CH2:12][CH2:13][CH:2]12.[H][H]>[Pd]>[CH:2]1([OH:1])[CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1

Participants

4

Reactant 2

HCID 791351,2-Epoxycyclododeca-5,9-dieneHCID 178418361HCID 178418361, compound

Product 1

HCID 15595CyclododecanolYield 5%

Reagents, catalysts & solvents 1

HCID 23938PalladiumCatalyst

Procedure

Also, the Drafted Report of 24th Symposium of Development in Reaction and Synthesis, Nov. 5 to 6, 1998, page 68, discloses a method of hydrogenating 1,2-epoxy-5,9-cyclododecadiene with hydrogen at ambient atmospheric pressure and room temperature in the presence of a catalyst comprising palladium carried on a carrier consisting of a carbon material. In this method, cyclododecanol was produced with a yield of 5% and no cyclododecanone was obtained.

Workup

  1. customAlso, the Drafted Report of 24th Symposium of Development in Reaction and Synthesis, Nov
  2. customat ambient atmospheric pressure and room temperature

Sources & evidence

ORD record
ord-785d35ff3b6a41479bea5a07af8690e0
Source dataset
uspto-grants-2002_01
Patent number
US06335472B1

Reaction notes

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