Cyclododecanone → 13-Oxabicyclo[10.1.0]tridecane

HRID 1250042Notes

Reaction equation

HRID 1250042 reaction equation
[CH:1]1([OH:13])[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.C1(=O)CCCCCCCCCCC1>>[O:13]1[CH:2]2[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH:1]12

Participants

3

Reactant 2

HCID 13246CyclododecanoneHCID 15595Cyclododecanol

Product 1

HCID 924813-Oxabicyclo[10.1.0]tridecane

Procedure

After the reaction was completed, the catalyst was removed from the reaction product mixture by filtering, and the reaction product mixture was subjected to gas chromatographic analysis. As a result, it was found that cyclododecanol was obtained in a yield of 6 molar % based on the fed epoxycyclododecadiene, and cyclododecanone was obtained in a yield of 76 molar %. Thus, the total yield of cyclododecanol and cyclododecanone was 82 molar %. In the reaction, epoxycyclododecane was produced in a yield of 16 molar %.

Workup

  1. customIn the reaction

Sources & evidence

ORD record
ord-3669fd70b92b47e5b249bda2f2d404ff
Source dataset
uspto-grants-2002_01
Patent number
US06335472B1

Reaction notes

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