HRID1250057

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CN(C)C=NS(=O)(=O)c1ccccc1-c1ccc(Cn2c(-c3ccccc3)nc(-c3ccccc3)c2-c2ccccc2)cc1

HCID70144593

未命名化合物

PRODUCTS

生成物

结构：NS(=O)(=O)c1ccccc1-c1ccc(Cn2c(-c3ccccc3)nc(-c3ccccc3)c2-c2ccccc2)cc1

HCID18400113

未命名化合物

收率 58%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID313

Hydrochloric Acid

ClH

溶剂HCID702

Ethanol

C2H6O

PROCEDURE

实验过程

1.9 g of 4′-(2,4,5-triphenylimidazol-1-ylmethyl)biphenyl-2-sulfonic acid dimethylaminomethylenamide in 20 ml of ethanol and 20 ml of a saturated aqueous HCl solution are refluxed for 3 h. The volatile constituents are removed in vacuo, the residue is stirred with 100 ml of water and the product is filtered off. 1.0 g of an amorphous powder is obtained.

WORKUP

后处理

customThe volatile constituents are removed in vacuo
filtrationthe product is filtered off

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-c90a902d671341aa83df223619bd6e8b
来源数据集: uspto-grants-2002_01
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06335451B1
来源说明: uspto-grants-2002_01

反应 SMILES

CN(C=[N:5][S:6]([C:9]1[C:10]([C:15]2[CH:20]=[CH:19][C:18]([CH2:21][N:22]3[C:26]([C:27]4[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=4)=[C:25]([C:33]4[CH:38]=[CH:37][CH:36]=[CH:35][CH:34]=4)[N:24]=[C:23]3[C:39]3[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=3)=[CH:17][CH:16]=2)=[CH:11][CH:12]=[CH:13][CH:14]=1)(=[O:8])=[O:7])C>C(O)C.Cl>[C:39]1([C:23]2[N:22]([CH2:21][C:18]3[CH:17]=[CH:16][C:15]([C:10]4[C:9]([S:6]([NH2:5])(=[O:8])=[O:7])=[CH:14][CH:13]=[CH:12][CH:11]=4)=[CH:20][CH:19]=3)[C:26]([C:27]3[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=3)=[C:25]([C:33]3[CH:34]=[CH:35][CH:36]=[CH:37][CH:38]=3)[N:24]=2)[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=1