4-Toluenesulfonyl chloride → HCID 53762787, compound

HRID 1252668Notes

Reaction equation

HRID 1252668 reaction equation
C(O)[CH:2]([OH:8])[CH2:3][CH2:4][CH2:5]CC.C1(C)C=CC(S(Cl)(=O)=O)=CC=1.[C:21]1([CH3:39])[CH:26]=[CH:25][C:24]([S:27]([O:30][CH2:31][CH:32]([OH:38])[CH2:33][CH2:34][CH2:35][CH2:36][CH3:37])(=[O:29])=[O:28])=[CH:23][CH:22]=1>N1C=CC=CC=1>[C:2]([O:38][CH:32]([CH2:33][CH2:34][CH2:35][CH2:36][CH3:37])[CH2:31][O:30][S:27]([C:24]1[CH:23]=[CH:22][C:21]([CH3:39])=[CH:26][CH:25]=1)(=[O:28])=[O:29])(=[O:8])[CH2:3][CH2:4][CH3:5]

Participants

5

Reactant 3

HCID 73974-Toluenesulfonyl chlorideHCID 773021,2-HeptanediolHCID 19105686HCID 19105686, compound

Product 1

HCID 53762787HCID 53762787, compound

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

Using 1,2-heptanediol, pyridine and p-toluenesulfonyl chloride, (RS)-1-p-toluenesulfonyloxy-2-heptanol 2c ##STR26## was prepared in the same manner as Example 1 of Production.

Workup

  1. customwas prepared in the same manner as Example 1 of Production

Sources & evidence

ORD record
ord-55ec4bf4983e48f4b435ac52416614c1
Source dataset
uspto-grants-1988_05
Patent number
US04745066

Reaction notes

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