Sodium Chloride → HCID 792532, compound

HRID 1253048Notes

Reaction equation

HRID 1253048 reaction equation
[Na].[CH:2]1[C:15]2[C:14](=[O:16])[C:13](=[N:17][OH:18])[C:12]3[C:7](=[CH:8][CH:9]=[CH:10][CH:11]=3)[C:6]=2[CH:5]=[CH:4][CH:3]=1.[C:19](Cl)(=[O:26])[C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1.[Cl-].[Na+]>CC(C)=O>[C:19]([O:18][N:17]=[C:13]1[C:14](=[O:16])[C:15]2[CH:2]=[CH:3][CH:4]=[CH:5][C:6]=2[C:7]2[C:12]1=[CH:11][CH:10]=[CH:9][CH:8]=2)(=[O:26])[C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1

Participants

6

Reactant 4

HCID 5234Sodium ChlorideHCID 7412Benzoyl chlorideHCID 5360545SodiumHCID 178516814HCID 178516814, compound

Product 1

HCID 792532HCID 792532, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent2×

Procedure

24.6 g (0.1 mole) of the sodium salt of 9,10-phenanthrene-dione-9-oxime are suspended in 100 ml of acetone, whereupon a solution of 15.4 g (0.11 mole) of benzoyl chloride and 50 ml of acetone is added under stirring. A slightly exothermic reaction takes place, sodium chloride is precipitated and within about an hour a dark brown solution is formed. The reaction having been completed, the reaction mixture is heated to boiling for 15 minutes and evaporated in vacuo. Thus 28.2 g of 9,10-phenanthrene-dione-9-benzoyl-oxime are obtained, yield, 86.2%, mp.: 148°-149° C.

Workup

  1. additionis added
  2. customA slightly exothermic reaction
  3. customis precipitated and within about an hour a dark brown solution
  4. customis formed
  5. temperaturethe reaction mixture is heated
  6. customevaporated in vacuo

Sources & evidence

ORD record
ord-21c7b2947fab40e3b5e37d3b006f80f4
Source dataset
uspto-grants-1988_05
Patent number
US04746678

Reaction notes

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