Butyl isocyanate → HCID 54030194, compound

HRID 1253050Notes

Reaction equation

HRID 1253050 reaction equation
[CH:1]1[C:14]2[C:13](=[O:15])[C:12](=[N:16][OH:17])[C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH:4]=[CH:3][CH:2]=1.[CH2:18]([N:22]=[C:23]=[O:24])[CH2:19][CH2:20][CH3:21].C(N(CC)CC)C>C(Cl)(Cl)Cl>[CH2:18]([NH:22][C:23]([O:17][N:16]=[C:12]1[C:13](=[O:15])[C:14]2[CH:1]=[CH:2][CH:3]=[CH:4][C:5]=2[C:6]2[C:11]1=[CH:10][CH:9]=[CH:8][CH:7]=2)=[O:24])[CH2:19][CH2:20][CH3:21]

Participants

5

Reactant 3

HCID 8110Butyl isocyanateHCID 8471TriethylamineHCID 178516814HCID 178516814, compound

Product 1

HCID 54030194HCID 54030194, compoundYield 99.3%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

22.3 g (0.1 mole) of 9,10-phenanthrene-dione-9-oxime are reacted with 12 ml (0.11 mole) of n-butyl isocyanate in 100 ml of chloroform in the presence of 0.2 ml of triethyl amine for an hour. The reaction mixture is heated to boiling for half an hour and evaporated in vacuo. Thus 32 g of 9,10-phenanthrene-dione-9-(n-butyl-aminocarbonyl)-oxime are obtained in the form of a yellowish brown oil, yield 99%.

Workup

  1. temperatureThe reaction mixture is heated
  2. waitto boiling for half an hour
  3. customevaporated in vacuo

Sources & evidence

ORD record
ord-7038ea2b7f184fe4b85ddde27ee0fc11
Source dataset
uspto-grants-1988_05
Patent number
US04746678

Reaction notes

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