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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1253506Generated: November 1, 2026

Diethyl (ethoxymethylene)malonate → HCID 178471941, compound

https://huagongshe.com/reaction/1253506

Reaction equation

Participants

RoleNameHCIDCharge
ReactantDiethyl (ethoxymethylene)malonateHCID 6871—
Reactant3-AminopyridineHCID 10009—
ProductHCID 178471941HCID 178471941—

Reaction Conditions

Temperature110 °C

Reaction Steps

A 250 ml flask was charged with 3-Aminopyridine (8 g, 85 mmol) and diethyl 2-(ethoxymethylene)malonate (18.5 g, 85.6 mmol). The mixture was heated to 110° C. for 30 min, and then cooled to ambient temperature to give diethyl [(E)-(pyridin-3-ylimino)methyl]malonate.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS08455477B2
Source datasetuspto-grants-2013_06
ORD IDord-08063f79c21747b197f6046b99bc4873
Source noteuspto-grants-2013_06