Furan → HCID 13904348, compound

HRID 1255399Notes

Reaction equation

HRID 1255399 reaction equation
[Cl:1][C:2]1[C:4]([Cl:6])([Cl:5])[C:3]=1[Cl:7].[O:8]1[CH:12]=[CH:11][CH:10]=[CH:9]1>C1(C)C=CC=CC=1>[Cl:1][C:2]1[CH:9]2[O:8][CH:12]([C:4]([Cl:6])([Cl:5])[C:3]=1[Cl:7])[CH:11]=[CH:10]2

Participants

4

Reactant 2

HCID 8029FuranHCID 80428Tetrachlorocyclopropene

Product 1

HCID 13904348HCID 13904348, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

A stirred mixture of 1,2,3,3-tetrachlorocyclopropene (60 g) and furan (22.97 g) in dry toluene (600 ml) was heated to reflux for 30 hours. The solvent was evaporated under reduced pressure to afford the required product, 75.4 g. 1H NMR (CDCl3) δ: 6.90 (1H, dd), 6.45 (1H, dd), 5.41 (1H, d), 4.93 (1H, d).

Workup

  1. temperaturewas heated
  2. temperatureto reflux for 30 hours
  3. customThe solvent was evaporated under reduced pressure

Sources & evidence

ORD record
ord-6c8324c40aa7422f9f894984aa04e7f4
Source dataset
uspto-grants-2013_06
Patent number
US08461083B2

Reaction notes

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