HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Methylthiobenzaldehyde → HCID 86599977, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Methylthiobenzaldehyde | HCID 18177535 | — |
| Reactant | 1-[2-Hydroxy-4-ethoxycarbonyldimethylmethyloxyphenyl]-3-[3,5-ditertbutyl-4-hydroxyphenyl] prop-2-en-1-one | HCID 86599973 | — |
| Product | HCID 86599977 | HCID 86599977 | — |
Reaction Steps
This compound was synthesized from 2′-hydroxy-4′-ethyloxycarbonyldimethylmethyloxyacetophenone (starting material 1) and 4-methylthiobenzaldehyde according to general method 2 described earlier. Purification was by chromatography on silica gel (elution: cyclohexane/ethyl acetate 9/1) followed by preparative HPLC (reverse phase RP18, Licrospher 12 μm, elution: water/methanol/trifluoroacetic acid: 22/78/0.3).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08461212B2 |
| Source dataset | uspto-grants-2013_06 |
| ORD ID | ord-bd3bbd8d514c49ad88cb13dd876c7ca6 |
| Source note | uspto-grants-2013_06 |