Ammonium Chloride → HCID 69043906, compound

HRID 1259277Notes

Reaction equation

HRID 1259277 reaction equation
[F:1][C:2]1[CH:18]=[CH:17][C:5]([CH:6]=[C:7]2[C:15]3[CH2:14][CH2:13][CH2:12][CH2:11][C:10]=3[C:9](=[O:16])[O:8]2)=[CH:4][C:3]=1[N+:19]([O-])=O.[Cl-].[NH4+]>C(O)C.O.[Fe]>[NH2:19][C:3]1[CH:4]=[C:5]([CH:17]=[CH:18][C:2]=1[F:1])[CH:6]=[C:7]1[C:15]2[CH2:14][CH2:13][CH2:12][CH2:11][C:10]=2[C:9](=[O:16])[O:8]1

Participants

6

Reactant 2

HCID 25517Ammonium ChlorideHCID 69044850HCID 69044850, compound

Product 1

HCID 69043906HCID 69043906, compound

Reagents, catalysts & solvents 3

HCID 23925IronCatalystHCID 702EthanolSolventHCID 962WaterSolvent

Procedure

A solution of EXAMPLE 2A (2.25 g) and ammonium chloride (0.83 g) in ethanol (35 mL) and water (25 mL) at 70° C. was treated with iron powder (4.35 g), stirred for 3 hours and filtered through diatomaceous earth (CELITE™, World Minerals, Santa Barbara, Calif.) with hot ethanol. The filtrate was concentrated, and the concentrate was stirred with water for 30 minutes and filtered. The solid was washed with water and dried.

Workup

  1. filtrationfiltered through diatomaceous earth (CELITE™, World Minerals, Santa Barbara, Calif.) with hot ethanol
  2. concentrationThe filtrate was concentrated
  3. stirringthe concentrate was stirred with water for 30 minutes
  4. filtrationfiltered
  5. washThe solid was washed with water
  6. customdried

Sources & evidence

ORD record
ord-731f9d824b5d4dc3a8ae5612cfc6d8f6
Source dataset
uspto-grants-2013_06
Patent number
US08466150B2

Reaction notes

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