Ammonium Carbonate → HCID 12289429, compound

HRID 1262643Notes

Reaction equation

HRID 1262643 reaction equation
[ClH:1].C(O[C:5]([C:7]1[CH:12]=[CH:11][CH:10]=[C:9]([C:13](=[O:15])[CH3:14])[CH:8]=1)=[NH:6])C.C(=O)([O-])[O-].[NH4+:20].[NH4+]>C(O)C>[ClH:1].[C:13]([C:9]1[CH:8]=[C:7]([C:5](=[NH:6])[NH2:20])[CH:12]=[CH:11][CH:10]=1)(=[O:15])[CH3:14]

Participants

4

Reactant 2

HCID 517111Ammonium CarbonateHCID 12289426Benzenecarboximidic acid, 3-acetyl-, ethyl ester, hydrochloride

Product 1

HCID 12289429HCID 12289429, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

A mixture of 14 g. (0.08 mole) of 3-acetylbenzenecarboximidic acid ethyl ester, hydrochloride of A. above and 14 g. (0.15 mole) of finely ground ammonium carbonate in 100 ml. of ethanol is heated at boiling temperature in an open flask for 3 hours. The solution is cooled and the first small amount of precipitate is collected and is discarded. The filtrate is further cooled to precipitate 6.7 g. of product with a melting point of 193° (dec.).

Workup

  1. additionA mixture of 14 g
  2. customfor 3 hours
  3. temperatureThe solution is cooled
  4. customthe first small amount of precipitate is collected
  5. temperatureThe filtrate is further cooled
  6. customto precipitate 6.7 g

Sources & evidence

ORD record
ord-6bad46dd373641b885812a09cba79cd1
Source dataset
uspto-grants-1984_06
Patent number
US04452985

Reaction notes

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