Propanal → HCID 54368473, compound

HRID 1262722Notes

Reaction equation

HRID 1262722 reaction equation
[CH3:1][C:2]1=[CH:3][CH2:4][CH2:5][C:6]([C@@H:8]2[C@@H:11]([CH2:12][CH2:13]1)[C:10]([CH3:15])([CH3:14])[CH2:9]2)=[CH2:7].[CH:16](=[O:19])[CH2:17][CH3:18].C(OOC(C)(C)C)(C)(C)C>>[C:16]([CH:3]1[CH2:4][CH2:5][C:6]2([CH3:7])[C:2]1([CH3:1])[CH2:13][CH2:12][CH:11]1[CH:8]2[CH2:9][C:10]1([CH3:15])[CH3:14])(=[O:19])[CH2:17][CH3:18]

Participants

4

Reactant 3

HCID 527PropanalHCID 8033Di-tert-butyl peroxideHCID 5281522Isocaryophyllene

Product 1

HCID 54368473HCID 54368473, compound

Procedure

Above mentioned compound was prepared as described in example I from 80 g caryophyllene, 220 g propanal and 6 g di-tert.butyl peroxide in an ampoule of glass having a volume of 300 ml. Yield: 10 g reaction product; boiling point: 145°-150° C./0.3 kPa; nD23 =1.4930.

Workup

  1. customwas prepared
  2. customYield: 10 g reaction product

Sources & evidence

ORD record
ord-c0744ef7694443098323faaa42148898
Source dataset
uspto-grants-1984_06
Patent number
US04453014

Reaction notes

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