Lithium Hydroxide → HCID 13325399, compound

HRID 1262958Notes

Reaction equation

HRID 1262958 reaction equation
C([O:4][C@@H:5]1[C@@H:18]([O:19]C(=O)C)[C@H:17]([O:23]C(=O)C)[CH2:16][O:15][C@H:6]1[S:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14])(=O)C.[OH-].[Li+]>CO>[S:7]([CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14])[C@@H:6]1[O:15][CH2:16][C@@H:17]([OH:23])[C@H:18]([OH:19])[C@H:5]1[OH:4]

Participants

4

Reactant 2

HCID 3939Lithium HydroxideHCID 13325464HCID 13325464, compound

Product 1

HCID 13325399HCID 13325399, compoundYield 95%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

In 10 ml. of methanol was dissolved 2.45 g. of the compound (18), and 10 mg. of lithium hydroxide was added to the solution. The mixture was stirred at room temperature for one hour to yield the desired n-heptyl 1-thio-β-D-xylopyranoside which was a compound of the present invention. The yield was 95%.

Sources & evidence

ORD record
ord-ecb74554f4ad435890b045d8f8883df9
Source dataset
uspto-grants-1984_06
Patent number
US04454123

Reaction notes

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