HRID1263308

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID70370

2,6-Di-tert-butyl-4-mercaptophenol

C14H22OS

结构：O=C1C=CC(=O)N1c1ccc(N2C(=O)C=CC2=O)cc1

HCID76765

N,N'-4-Phenylenedimaleimide

C14H8N2O4

PRODUCTS

生成物

结构：CC(C)(C)c1cc(SC2CC(=O)N(c3ccc(N4C(=O)CC(Sc5cc(C(C)(C)C)c(O)c(C(C)(C)C)c5)C4=O)cc3)C2=O)cc(C(C)(C)C)c1O

HCID13547666

未命名化合物

收率 75.6%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID8471

Triethylamine

C6H15N

PROCEDURE

实验过程

The procedure of Example 1 is repeated using 17.8 grams of 2,6-di-tert-butyl-4-mercaptophenol, 10 grams of 1,4-bis(maleimido)benzene, and 0.75 grams of triethylamine. The residue is recrystallized from acetone to give 21 grams of an off-white solid, m.p. 274°-278° C.

WORKUP

后处理

customThe residue is recrystallized from acetone

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-b2ff3ff2a03c4dddbb8002f06af91f29
来源数据集: uspto-grants-1984_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04456716
来源说明: uspto-grants-1984_06

反应 SMILES

[C:1]([C:5]1[CH:10]=[C:9]([SH:11])[CH:8]=[C:7]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:6]=1[OH:16])([CH3:4])([CH3:3])[CH3:2].[C:17]1(=[O:36])[N:21]([C:22]2[CH:27]=[CH:26][C:25]([N:28]3[C:32](=[O:33])[CH:31]=[CH:30][C:29]3=[O:34])=[CH:24][CH:23]=2)[C:20](=[O:35])[CH:19]=[CH:18]1>C(N(CC)CC)C>[C:1]([C:5]1[CH:10]=[C:9]([S:11][CH:30]2[CH2:31][C:32](=[O:33])[N:28]([C:25]3[CH:26]=[CH:27][C:22]([N:21]4[C:20](=[O:35])[CH2:19][CH:18]([S:11][C:9]5[CH:8]=[C:7]([C:12]([CH3:13])([CH3:14])[CH3:15])[C:6]([OH:16])=[C:5]([C:1]([CH3:4])([CH3:3])[CH3:2])[CH:10]=5)[C:17]4=[O:36])=[CH:23][CH:24]=3)[C:29]2=[O:34])[CH:8]=[C:7]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:6]=1[OH:16])([CH3:4])([CH3:3])[CH3:2]