Potassium Carbonate → HCID 18615540, compound

HRID 1265270Notes

Reaction equation

HRID 1265270 reaction equation
Br[CH2:2][C:3]1[CH:8]=[C:7]([CH3:9])[CH:6]=[C:5]([CH2:10]Br)[C:4]=1[O:12][CH3:13].[CH3:14][N:15]1[CH2:23][CH2:22][NH:21][CH2:20][CH2:19][N:18]([CH3:24])[CH2:17][CH2:16]1.C([O-])([O-])=O.[K+].[K+]>C1(C)C=CC=CC=1>[CH3:24][N:18]1[CH2:17][CH2:16][N:15]([CH3:14])[CH2:23][CH2:22][N:21]([CH2:2][C:3]2[CH:8]=[C:7]([CH3:9])[CH:6]=[C:5]([CH2:10][N:21]3[CH2:22][CH2:23][N:15]([CH3:14])[CH2:16][CH2:17][N:18]([CH3:24])[CH2:19][CH2:20]3)[C:4]=2[O:12][CH3:13])[CH2:20][CH2:19]1

Participants

5

Reactant 3

HCID 11430Potassium CarbonateHCID 46107181,3-bis(bromomethyl)-2-methoxy-5-methylbenzeneHCID 129739721,4-Dimethyl-1,4,7-triazonane

Product 1

HCID 18615540HCID 18615540, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

0.31 g (1 mmol) of 2,6-bis bromomethyl-4-methylanisole are added over the course of 30 min to a solution of 0.31 g (2 mmol) of 1,4-dimethyl-1,4,7-triazacyclononane, 0.14 g of K2CO3 (1 mmol) in 10 ml of toluene, and the reaction mixture is refluxed under a protective gas for 2 days.

Workup

  1. temperaturethe reaction mixture is refluxed under a protective gas for 2 days

Sources & evidence

ORD record
ord-9e512895a86542c6a5e165b22d35dc6d
Source dataset
uspto-grants-2003_04
Patent number
US06545147B1

Reaction notes

Loading…