Stannous chloride dihydrate → HCID 69688133, compound

HRID 1265552Notes

Reaction equation

HRID 1265552 reaction equation
[C:1]([O:5][C:6](=[O:23])[NH:7][C:8]1[CH:13]=[C:12]([N:14]2[CH2:18][CH2:17][CH2:16][CH2:15]2)[C:11]([Cl:19])=[CH:10][C:9]=1[N+:20]([O-])=O)([CH3:4])([CH3:3])[CH3:2].O.O.Cl[Sn]Cl>>[C:1]([O:5][C:6](=[O:23])[NH:7][C:8]1[CH:13]=[C:12]([N:14]2[CH2:18][CH2:17][CH2:16][CH2:15]2)[C:11]([Cl:19])=[CH:10][C:9]=1[NH2:20])([CH3:4])([CH3:2])[CH3:3]

Participants

3

Reactant 2

HCID 61436Stannous chloride dihydrateHCID 69687712HCID 69687712, compound

Product 1

HCID 69688133HCID 69688133, compound

Procedure

The title compound was prepared from (4-chloro-2-nitro-5-pyrrolidin-1-yl-phenyl)-carbamic acid tert.-butyl ester (Example C8) by reduction with SnCl2.2H2O according to the general procedure J (method b). Obtained as a red solid (4.80 g).

Sources & evidence

ORD record
ord-287dfcb72d0442f2861603dbc7b1c6a5
Source dataset
uspto-grants-2003_04
Patent number
US06544985B2

Reaction notes

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