HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → 4-(4-Diazo-3-methyl-5-oxo-2-pyrazolin-1-yl)benzoic acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | p-Toluenesulfonyl azide | HCID 13661 | — |
| Reactant | 4-(3-Methyl-5-oxo-2-pyrazolin-1-yl)benzoic acid | HCID 109029 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | 4-(4-Diazo-3-methyl-5-oxo-2-pyrazolin-1-yl)benzoic acid | HCID 135502619 | — |
Reaction Steps
A solution of 4-(3-methyl-5-oxo-2-pyrazolin-1-yl)benzoic acid (5.0 g, 0.023 mol) and p-toluenesulfonylazide (5.03 g, 0.026 mol) in methanol (30.0 mL) was treated with triethylamine (5.2 g; 0.051 mol.) and the reaction was stirred at room temperature for 5 hours.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06552008B1 |
| Source dataset | uspto-grants-2003_04 |
| ORD ID | ord-e4ac385ef28a413c8cc30c3437ac2ecb |
| Source note | uspto-grants-2003_04 |