化工社化工社 化学情報印刷レポート · 研究参考用
Ethyl Acrylate → Methyl 4-nitrononanoate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ethyl Acrylate | HCID 8821 | — |
| 反応物 | Potassium Carbonate | HCID 11430 | — |
| 反応物 | 1-Nitrohexane | HCID 12589 | — |
| 触媒 | Trioctylmethylammonium chloride | HCID 21218 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | Methyl 4-nitrononanoate | HCID 10632556 | — |
反応手順
Ex-31a) A suspension of ethyl acrylate, 1-nitrohexane, K2CO3, and Aliquat 336 (6 drops) is sonicated for 5 h. To the reaction is added Et2O . The reaction mixture is filtered, extracted with brine, dried over Na2SO4 (anhydrous), filtered, and concentrated under reduced pressure to give a yellow liquid. The product is purified by column chromatography to give methyl 4-nitrononanoate.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US06552052B2 |
| 出典データセット | uspto-grants-2003_04 |
| ORD ID | ord-83dc01ddeaa3479db0bbfe65bd494140 |
| 出典メモ | uspto-grants-2003_04 |