Diethyl Malonate → Ethyl 2-(3,3,4,4,5,5,6,6,6-nonafluorohexyl)-9-decenoate

HRID 1267479Notes

Reaction equation

I[CH2:2][CH2:3][C:4]([F:16])([F:15])[C:5]([F:14])([F:13])[C:6]([F:12])([F:11])[C:7]([F:10])([F:9])[F:8].[C:17](OCC)(=O)[CH2:18][C:19]([O:21][CH2:22][CH3:23])=[O:20].I[CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH:35]=C>>[F:15][C:4]([F:16])([C:5]([F:14])([F:13])[C:6]([F:12])([F:11])[C:7]([F:10])([F:9])[F:8])[CH2:3][CH2:2][CH:18]([CH2:17][CH2:35][CH2:34][CH2:33][CH2:32][CH2:31][CH:30]=[CH2:29])[C:19]([O:21][CH2:22][CH3:23])=[O:20]

Participants

Reactant 3

HCID 7761Diethyl Malonate

HCID 748871,1,1,2,2,3,3,4,4-Nonafluoro-6-iodohexane

HCID 138898108-Iodooct-1-ene

Product 1

HCID 22718077Ethyl 2-(3,3,4,4,5,5,6,6,6-nonafluorohexyl)-9-decenoate

Procedure

Starting with 1-iodo-3,3,4,4,5,5,6,6,6-nonafluorohexane, diethyl malonate and 8-iodooct-1-ene, the analogous procedure as shown in Example 3, 4 or 5 was repeated to give ethyl 2-(3,3,4,4,5,5,6,6,6-nonafluorohexyl)-9-decenoate.

Sources & evidence

ORD record: ord-e44f910cd854416e9c699447c396aa88
Source dataset: uspto-grants-2003_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06552069B1

Reaction notes

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