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HRID126796

反应详情

EQUATION

反应方程式

HRID 126796 的结构方程式

REACTANTS

反应物

1
结构：CCCCCC(C)C(C)c1cc(O)c2c(c1)OC(C)(C)C1=C2CNCC1
HCID213543

5,5-Dimethyl-8-(3-methyloctan-2-yl)-1,3,4,5-tetrahydro-2H-[1]benzopyrano[4,3-c]pyridin-10-ol

C23H35NO2

PRODUCTS

生成物

1
结构：CCCCCC(C)C(C)c1cc(O)c2c(c1)OC(C)(C)c1ccncc1-2
HCID19781402

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：[Pd]
催化剂HCID23938

Palladium

Pd

结构：Cc1ccccc1C
溶剂HCID7237

o-Xylene

C8H10

PROCEDURE

实验过程

A mixture of 4.20 g. of 5,5-dimethyl-10-hydroxy-8-(3-methyl-2-octyl)-1,2,3,4-tetrahydro-5H-[1]benzopyrano[3,4-d]pyridine, 0.8 g. of 10% palladium on carbon and 80 ml. of xylene was stirred and refluxed for 25 hours. After cooling, the catalyst was removed by filtration. The filtrate was evaporated in vacuo and the product was recrystallized from autonitrile; m.p. 155°-157°.

WORKUP

后处理

  1. additionA mixture of 4.20 g
  2. temperaturerefluxed for 25 hours
  3. temperatureAfter cooling
  4. customthe catalyst was removed by filtration
  5. customThe filtrate was evaporated in vacuo
  6. customthe product was recrystallized from autonitrile