Diisobutylaluminum hydride → HCID 69796166, compound

HRID 1268308Notes

Reaction equation

CC(C[AlH]CC(C)C)C.[C:10]([C:14]1[CH:19]=[CH:18][C:17]([C:20]2[CH:25]=[CH:24][C:23](/[C:26](/[CH3:33])=[CH:27]/[C:28](OCC)=[O:29])=[CH:22][CH:21]=2)=[CH:16][CH:15]=1)([CH3:13])([CH3:12])[CH3:11]>>[C:10]([C:14]1[CH:19]=[CH:18][C:17]([C:20]2[CH:21]=[CH:22][C:23](/[C:26](/[CH3:33])=[CH:27]/[CH2:28][OH:29])=[CH:24][CH:25]=2)=[CH:16][CH:15]=1)([CH3:13])([CH3:11])[CH3:12]

Participants

Reactant 2

HCID 14487Diisobutylaluminum hydride

HCID 22557558HCID 22557558, compound

Product 1

HCID 69796166HCID 69796166, compound

Procedure

The colourless gum (E)-3-(4′-tert-butyl-biphenyl-4-yl)-but-2-en-1-ol was prepared by DIBAL-H reduction of (E)-ethyl 3-(4′-tert-butyl-biphenyl-4-yl)-but-2-enoate by a procedure analogous to that described in example 52b.

Sources & evidence

ORD record: ord-a016418a28104229a29d363597234657
Source dataset: uspto-grants-2003_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06555577B1

Reaction notes

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