Diisobutylaluminum hydride → HCID 22557582, compound

HRID 1268324Notes

Reaction equation

HRID 1268324 reaction equation
CC(C[AlH]CC(C)C)C.[C:10]1([C:16]2[CH:21]=[C:20](/[CH:22]=[CH:23]/[C:24](OCC)=[O:25])[CH:19]=[C:18]([C:29]3[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=3)[CH:17]=2)[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1>>[C:10]1([C:16]2[CH:21]=[C:20](/[CH:22]=[CH:23]/[CH2:24][OH:25])[CH:19]=[C:18]([C:29]3[CH:30]=[CH:31][CH:32]=[CH:33][CH:34]=3)[CH:17]=2)[CH:11]=[CH:12][CH:13]=[CH:14][CH:15]=1

Participants

3

Reactant 2

HCID 14487Diisobutylaluminum hydrideHCID 22557638HCID 22557638, compound

Product 1

HCID 22557582HCID 22557582, compound

Procedure

The colourless solid (E)-3-[1,1′;3′,1″]terphenyl-5′-yl-prop-2-en-1-ol was prepared by DIBAL-H reduction of (E)-ethyl 3-[1,1′;3′,1″]terphenyl-5′-yl-acrylate by a procedure analogous to that described for example 52b.

Sources & evidence

ORD record
ord-1c8d99c3ef5b4877b0f7bb15ddc0a586
Source dataset
uspto-grants-2003_04
Patent number
US06555577B1

Reaction notes

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