Diisobutylaluminum hydride → HCID 69800282, compound

HRID 1268329Notes

Reaction equation

HRID 1268329 reaction equation
CC(C[AlH]CC(C)C)C.[CH3:10][O:11][C:12]1[CH:13]=[C:14]([C:18]2[CH:23]=[CH:22][C:21](/[C:24](/[CH3:31])=[CH:25]/[C:26](OCC)=[O:27])=[CH:20][CH:19]=2)[CH:15]=[CH:16][CH:17]=1>>[CH3:10][O:11][C:12]1[CH:13]=[C:14]([C:18]2[CH:23]=[CH:22][C:21](/[C:24](/[CH3:31])=[CH:25]/[CH2:26][OH:27])=[CH:20][CH:19]=2)[CH:15]=[CH:16][CH:17]=1

Participants

3

Reactant 2

HCID 14487Diisobutylaluminum hydrideHCID 22557669HCID 22557669, compound

Product 1

HCID 69800282HCID 69800282, compound

Procedure

The colourless solid (E)-3-(3′-methoxy-biphenyl-4-yl)-but-2-en-1-ol was prepared by DIBAL-H reduction of (E)-ethyl 3-(3′-methoxy-biphenyl-4-yl)-but-2-enoate as described for example 52b.

Sources & evidence

ORD record
ord-797c1e6e1ace4157855e5990a49c556c
Source dataset
uspto-grants-2003_04
Patent number
US06555577B1

Reaction notes

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