Diisobutylaluminum hydride → HCID 69800699, compound

HRID 1268331Notes

Reaction equation

[Br:1][C:2]1[CH:3]=[C:4](/[C:9](/[CH3:16])=[CH:10]/[C:11](OCC)=[O:12])[CH:5]=[C:6]([Br:8])[CH:7]=1.CC(C[AlH]CC(C)C)C>>[Br:1][C:2]1[CH:3]=[C:4](/[C:9](/[CH3:16])=[CH:10]/[CH2:11][OH:12])[CH:5]=[C:6]([Br:8])[CH:7]=1

Participants

Reactant 2

HCID 14487Diisobutylaluminum hydride

HCID 22557634HCID 22557634, compound

Product 1

HCID 69800699HCID 69800699, compound

Procedure

(E)-Ethyl 3-(3,5-dibromophenyl)-but-2-enoate was reduced with DIBAL-H by a procedure analogous to that described in example 50b, to give the colourless oil (E)-3-(3,5-dibromophenyl)-but-2-en-1-ol.

Sources & evidence

ORD record: ord-f1bbd85043b84bf4a7a75233e34be87a
Source dataset: uspto-grants-2003_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06555577B1

Reaction notes

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