Diisobutylaluminum hydride → HCID 16215690, compound

HRID 1268334Notes

Reaction equation

HRID 1268334 reaction equation
[Br:1][C:2]1[CH:3]=[C:4](/[CH:9]=[CH:10]/[C:11](OCC)=[O:12])[CH:5]=[C:6]([Br:8])[CH:7]=1.CC(C[AlH]CC(C)C)C>>[Br:1][C:2]1[CH:3]=[C:4](/[CH:9]=[CH:10]/[CH2:11][OH:12])[CH:5]=[C:6]([Br:8])[CH:7]=1

Participants

3

Reactant 2

HCID 14487Diisobutylaluminum hydrideHCID 16215805HCID 16215805, compound

Product 1

HCID 16215690HCID 16215690, compound

Procedure

(E)-Ethyl 3-(3,5-dibromophenyl)-acrylate (example109a) was reduced with DIBAL-H by a procedure analogous to that described in example 50b, to give the colourless solid (E)-3-(3,5-dibromophenyl)-prop-2-en-1-ol.

Sources & evidence

ORD record
ord-91a46e30519b454197039896726a322d
Source dataset
uspto-grants-2003_04
Patent number
US06555577B1

Reaction notes

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