HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diisobutylaluminum hydride → (E)-3-(3',5'-dibromo-biphenyl-4-yl)-but-2-en-1-ol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diisobutylaluminum hydride | HCID 14487 | — |
| Reactant | (E)-ethyl 3-(3',5'-dibromo-biphenyl-4-yl)-but-2-enoate | HCID 22557684 | — |
| Product | (E)-3-(3',5'-dibromo-biphenyl-4-yl)-but-2-en-1-ol | HCID 69800831 | — |
Reaction Steps
The colourless gum (E)-3-(3′,5′-dibromo-biphenyl-4-yl)-but-2-en-1-ol was prepared by DIBAL-H reduction of (E)-ethyl 3-(3′,5′-dibromo-biphenyl-4-yl)-but-2-enoate as described for example 52b, with the purification of the product being carried out by preparative HPLC.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06555577B1 |
| Source dataset | uspto-grants-2003_04 |
| ORD ID | ord-60c23cb0f29f426db77f5286ca6c3195 |
| Source note | uspto-grants-2003_04 |